Yazar "Bulut, Adnan" için listeleme
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1,4-diferrocenylbutane-1,4-dione
Tombul, Mustafa; Bulut, Adnan; Guven, Kutalmis; Buyukgungor, Orhan (Blackwell Publishing, 2008)In the crystal structure of the title compound, [Fe-2(C5H5)(2)-(C14H12O2)], each carbonyl group is coplanar with the adjacent cyclopentadienyl ring, thus maximizing the pi-orbital overlap and electronic interactions between ... -
Application of FAM ligands in the metal-promoted catalytic enantioselective synthesis of organic compounds
Dogan, Oezdemir; Garner, Philip P.; Bulut, Adnan (Scientific Technical Research Council Turkey-Tubitak, 2009)Novel ferrocenyl substituted aziridinyl methanol (FAM) ligands were synthesized and successfully used in metal-promoted catalytic enantioselective azomethine ylide cycloadditions, diethylzinc additions to enones, alkynylzinc ... -
Asimetrik diferrosenil kiral türevlerin sentezi
Bulut, Adnan; Kırıkkale Üniversitesi, Rektörlük, Projeler (KırıkkaleKırıkkale Üniversitesi, 9999)… -
Aziridin bazlı yeni bir kiral ligand ile asimetrik henry tepkimesi
Aslan, Ayhan (Kırıkkale Üniversitesi, 2009)Bu tezde aldehit ve ß-ketoesterlere asimetrik nitrometan katılması (Henry reaksiyonu) çalışılmıştır. 4 adet kiral FAM (ferrosenil aziridinil metanol) diasteromerik stereoizomerleri sentezlenmiş ve kiral katalizör olarak ... -
Catalytic asymmetric nitroaldol (Henry) reaction with a zinc-Fam catalyst
Bulut, Adnan; Aslan, Ayhan; Dogan, Oezdemir (Amer Chemical Soc, 2008)Ferrocenyl-substituted aziridinylmethanol (Fam-1) was used as a catalyst with zinc for the asymmetric nitroaldol (Henry) reaction. This catalyst worked with a variety of aldehydes (aromatic, aliphatic, alpha,beta-unsaturated, ... -
Catalytic enantioselective addition of diethylzinc to aldehydes using aziridine based chiral ligands
Bulut, Adnan; Aslan, Ayhan; Izgu, Enver Cagri; Dogan, Oezdemir (Pergamon-Elsevier Science Ltd, 2007)The readily available ferrocenyl substituted aziridinylmethanol 1 (FAM-1) was used as a chiral catalyst in the diethylzinc addition reaction to aromatic and aliphatic aldehydes to give secondary alcohols in high yields and ... -
Chiral phosphine oxide aziridinyl phosphonate as a Lewis base catalyst for enantioselective allylsilane addition to aldehydes
Dogan, Ozdemir; Bulut, Adnan; Tecimer, M. Ali (Pergamon-Elsevier Science Ltd, 2015)A series of chiral Lewis bases, phosphine oxide ferrocenyl aziridinyl methanol 1-4, phosphinyl aziridinyl phosphonates 5 and 6, and phosphine oxide aziridinyl phosphonates 7 and 8 were screened for allylsilane additions ... -
Copper-catalyzed asymmetric conjugate addition of diethylzinc to substituted chalcones using a chiral phosphine ligand
Dogan, Ozdemir; Bulut, Adnan; Polat, Savas; Tecimer, M. Ali (Pergamon-Elsevier Science Ltd, 2011)A series of chiral phosphine PFAM and phosphine oxide POFAM ligands were studied for the copper-catalyzed asymmetric diethylzinc addition to enones. One of these ligands, PFAM2, was an efficient catalyst with a variety of ... -
Crystal structure of dimethylammonium bis(naphthalene-2,3-diolato) borate, C22H20BNO4
Tombul, Mustafa; Guven, Kutalmis; Bulut, Adnan; Svoboda, Ingrid; Fuess, Hartmut (Walter De Gruyter Gmbh, 2018)C22H20BNO4, monoclinic, C2/c (no. 15), a = 32.303(4) angstrom, b = 8.2703(6) angstrom, c = 7.3876(6) angstrom, beta = 92.889(8)degrees, V = 1971.1(3) angstrom(3), Z = 4, R-gt(F) = 0.0978, wR(ref)(F-2) = 0.2063, T = 298 K. -
Ferrosen Sübstitüe Aziridine Bileşiklerinin Sentezi
Bulut, Adnan; Doğan, Özdemir; Koyuncu, Hasan; Kırıkkale Üniversitesi, Rektörlük, Projeler (KırıkkaleKırıkkale Üniversitesi, 2003)… -
Imınlere asımetrık katılmalar
İnce, Akın (Kırıkkale Üniversitesi, 2010)Bu çalışmada Tosil imine asimetrik olarak dietilçinko, nitrometan (Aza-Henry) ve propargil katılması çalışılmıştır. Yapılan asimetrik reaksiyonlarda kiral ligand olarak FAM ve P-FAM katalizörleri kullanılmıştır. Çalışmada ... -
Karbonhidratların yeni tosil, azid ve amin türevleri sentezleri
Bulut, Adnan; Kırıkkale Üniversitesi, Rektörlük, Projeler (KırıkkaleKırıkkale Üniversitesi, 2014)… -
Kiral heteroril ferrosenil alkollerin sentezi ve biyolojik aktivitesinin incelenmesi
Bulut, Adnan; Kırıkkale Üniversitesi, Rektörlük, Projeler (KırıkkaleKırıkkale Üniversitesi, 2017)… -
New zinc(II)-based catalyst for asymmetric azomethine ylide cycloaddition reactions
Dogan, Ozdemir; Koyuncu, Hasan; Garner, Philip; Bulut, Adnan; Youngs, Wiley J.; Panzner, Matthew (Amer Chemical Soc, 2006)A new chiral aziridino alcohol ligand for zinc(II)-catalyzed azomethine ylide cycloadditions is described. In the presence of this catalyst, N-arylidene glycine methyl esters react with a variety of dipolarophiles to give ... -
Non-Acidic Mediated Friedel-Craft Reaction of Thiophene Using EtAlCl2
Unver, Halil; Biyikoglu, Mutluhan; Bulut, Adnan (Asian Journal Of Chemistry, 2013)Since alkyl Lewis acids are Bronsted bases, they give a non-acidic reaction media. In this context, acylation of thiophene is investigated in the presence of EtAlCl2 and non-acidic media. Besides 8 examples of thiophene, ... -
ORGN 188-A new method for the synthesis of racemic and chiral aziridine 2-phosphonates
Dogan, Ozdemir; Bulut, Adnan; Aslan, Ayhan; Tan, Serkan; Babiz, Hakan (Amer Chemical Soc, 2009)… -
Pyrolysis of Table Sugar
Bulut, Adnan; Karagoz, Selhan (Hindawi Publishing Corporation, 2013)Table sugars were pyrolyzed at different temperatures (300, 400, and 500 degrees C) in a fixed-bed reactor. The effect of pyrolysis temperature on yields of liquid, solid, and gaseous products was investigated. As expected ... -
Synthesis and biological activity of ferrocenyl furoyl derivatives
Tombul, Mustafa; Bulut, Adnan; Turk, Mustafa; Ucar, Busra; Isilar, Ozer (Taylor & Francis Inc, 2017)Due to the fact that ferrocene and furan derivatives have long been known to be one of the most biologically active compounds, preparation of their new derivatives might serve a very important purpose. Herein, five furoyl ... -
Synthesis and biological evaluation of novel urea, thiourea and squaramide diastereomers possessing sugar backbone
Isilar, Ozer; Bulut, Adnan; Yaglioglu, Ayse Sahin; Demirtas, Ibrahim; Arat, Esra; Turk, Mustafa (ELSEVIER SCI LTD, 2020)A series of novel chiral 14 urea, thiourea and squaramide stereoisomers possessing carbohydrate backbones as well as amide functional groups was synthesized and characterized by their, H-1 NMR, C-13 NMR, FT-IR, HRMS, optical ...